Good Cosmetic Ingredient NOAEL Data SCCS/CIR Reviewed

Hydroxyethyl-3,4-Methylenedioxyaniline HCl

Also known as: EINECS 303-085-5, UNII-8IRK9YBY3K

INCI: HYDROXYETHYL-3,4-METHYLENEDIOXYANILINE HCL

Hydroxyethyl-3,4-Methylenedioxyaniline HCl (CAS 94158-14-2) is a cosmetic cosmetic ingredient functioning as Oxidative hair dye precursor (coupler). NOAEL 20 mg/kg bw/day (cross-referenced against ToxValDB ECHA IUCLID); EU Regulation 1223/2009 status: restricted, max 1.5%; 3 safety opinions reviewed (cir). Industrial safety data is also available in the chemical safety database.

View industrial chemical safety profile for CAS 94158-14-2 →

Auto-generated CPSR Part A draft with source citations
Function
Oxidative hair dye precursor (coupler)
Safety Rating
GOOD

Chemistry & Identifiers

Formula
C9H12ClNO3
MW
217.65 g/mol
EC Number
303-085-5
PubChem CID
175592
IUPAC Name
2-(1,3-benzodioxol-5-ylamino)ethanol;hydrochloride
InChIKey
LMONVTDNVNEAQG-UHFFFAOYSA-N

Regulatory Status

EU EU Status restricted
EU Max Conc. 1.5%
US US Status permitted
US Notes Permitted under coal tar hair dye exemption; CIR concluded safe in present practices of use (2022)

For full compliance data across multiple jurisdictions, use the Substance Compliance tool.

Safety Data

Margin of Safety, dermal absorption, and sensitization profile summaries for Hydroxyethyl-3,4-Methylenedioxyaniline HCl.

Calculate MoS for your specific formulation with the MoS Calculator.

Toxicological Studies

10 study endpoints found for Hydroxyethyl-3,4-Methylenedioxyaniline HCl. NOAEL (No Observed Adverse Effect Level) values are used to calculate the Margin of Safety per SCCS methodology.

Endpoint Value Route Species Study Type Source
NOAEL =20 mg/kg/d oral rat developmental toxicity CIR_vision_codex
NOAEL =20 mg/kg/d oral rat developmental toxicity CIR_vision_codex
NOAEL =20 mg/kg/d oral rat developmental toxicity CIR_vision_codex
NOAEL =20 mg/kg/d oral rat developmental toxicity CIR_vision_codex
NOAEL =26 mg/kg/d - mouse developmental toxicity CIR_vision_codex
NOAEL =26 mg/kg/d - mouse developmental toxicity CIR_vision_codex
NOAEL =26 mg/kg/d - mouse developmental toxicity CIR_vision_codex
NOAEL =26 mg/kg/d - mouse developmental toxicity CIR_vision_codex
NOAEL 20 mg/kg bw/day oral rat Subchronic COSMOS_DB
NOAEL =20 mg/kg bw/day - rat genotoxicity SCCS_vision_codex

Safety Opinions

Official safety assessments from the Scientific Committee on Consumer Safety (SCCS) and Cosmetic Ingredient Review (CIR).

cir
Verdict: unknown
NOAEL: 20 mg/kg/d (not specified)
cir
Verdict: unknown
NOAEL: 26 mg/kg/d (not specified)
cir
Verdict: unknown
NOAEL: 20 mg/kg/d (oral)

Pre-Calculated Safety Assessment

Pre-calculated NOAEL → SED → MoS audit trail for Hydroxyethyl-3,4-Methylenedioxyaniline HCl across SCCS product categories, with measured dermal absorption where available.

ECHA REACH Registration

European Chemicals Agency REACH dossier and Substances of Very High Concern listing.

Registration Type
Full
Tonnage Band
10 - 100 tonnes
Substance Type
SUBSTANCE
SVHC Candidate
No

Expanded Jurisdictional Detail

Additional regulatory detail beyond the 7-jurisdiction summary: Saudi SFDA, Korea MFDS, ASEAN ACD, Japan/Korea, Brazil/India, and cross-jurisdictional restriction entries.

SA Saudi SFDA (III - Restricted)
Product type: Hair dye substance in oxidative hair dye products.
BRIN Brazil/India Cosmetics
India: Restricted

Expanded Dermal Absorption Data

Cross-database dermal penetration: EPA Dryad physics-based, Roberts Mendeley permeation, and SCCS-aggregated measured values.

Aggregated DA Values (5 records across 5 sources)
Type DA % Method Skin Model SCCS Ref
measured 2.0% - - SCCP/0044
measured 1.5% - - SCCP/0044
measured 97.0% - - SCCP/0044
measured 1.4% - - SCCP/0044
measured 2.1% - - SCCP/0044

Additional Ingredient Properties

1 property record from structured ingredient metadata.

hair_dye
{"cas_number": "94158-14-2", "ingredient_class": "oxidative_dye_coupler", "chemical_class": "other", "molecular_weight_Da": "217.65", "color_result_on_hair": "Ash-violet modifier", "shade_range": "brown", "primary_function": "coupler", "oxidative_dye_type": "coupler", "requires_developer": "yes", "permanence": "permanent", "oxidation_mechanism": "coupling", "hair_penetration_depth": "cortex", "sen…

Function Categories & List Membership

Cosmetic/Chemical Function Categories
Dye
Regulatory List Membership (1)
EU CosIng Cosmetics Ingredient Database

Expert Verdict

Expert safety assessment and concern-level summary for Hydroxyethyl-3,4-Methylenedioxyaniline HCl.

Regulatory Flags

potential-allergen eu_cosing_listed

NOAEL Studies Summary

View details ->

Public NOAEL study rows linked to Hydroxyethyl-3,4-Methylenedioxyaniline HCl by CAS number or substance name.

Studies
27
Lowest NOAEL
20
Highest NOAEL
50

Units vary across source rows: mg/kg bw/day, mg/kg/d, mg/kg bw

COSMOS_DB ToxValDB_ECHA_IUCLID CIR_vision_codex SCCS_vision_codex

Dermal Absorption

View details ->
Absorption % Method Vehicle
2.0% - -
1.5% - -
97.0% - -
1.4% - -
2.1% - -

Known Synonyms

EINECS 303-085-5 UNII-8IRK9YBY3K

Chemical Function

Dye

Regulatory Lists

Europe; Personal care; restricted Canada; Personal care; Substances in PCP - Canada (4/2014) Europe; Personal care - hair coloring

Australian Status

AICIS status: listed

Frequently Asked Questions

Is Hydroxyethyl-3,4-Methylenedioxyaniline HCl safe in cosmetics?

Hydroxyethyl-3,4-Methylenedioxyaniline HCl has a safety rating of "GOOD" in our database. EU status: restricted. US status: permitted. 10 toxicological study endpoint(s) are available in our database. This ingredient has been reviewed by cir.

Is Hydroxyethyl-3,4-Methylenedioxyaniline HCl allowed in the EU?

Hydroxyethyl-3,4-Methylenedioxyaniline HCl EU regulatory status: restricted. Maximum allowed concentration: 1.5%. This is based on EU Regulation 1223/2009 and its amendments.

What does Hydroxyethyl-3,4-Methylenedioxyaniline HCl do in cosmetics?

Hydroxyethyl-3,4-Methylenedioxyaniline HCl functions as: Oxidative hair dye precursor (coupler). It is classified as a cosmetic ingredient in our database. CAS number: 94158-14-2.

What is the NOAEL for Hydroxyethyl-3,4-Methylenedioxyaniline HCl?

The NOAEL (No Observed Adverse Effect Level) for Hydroxyethyl-3,4-Methylenedioxyaniline HCl is =20 mg/kg/d based on a developmental toxicity study via oral route in rat. A total of 10 study endpoints are available. Source: CIR_vision_codex.

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