Aluminum Chlorohydrate

Also known as: Aluminium chloride hydroxide (Al2Cl(OH)5), Basic aluminum chloride [Al2(OH)5Cl], Aluminum chlorhydrol, Basic aluminum chlorate, EINECS 234-933-1 (+7 more)

INCI: ALUMINUM CHLOROHYDRATE

Aluminum Chlorohydrate (CAS 12042-91-0) is a cosmetic active ingredient functioning as antiperspirant, astringent, deodorant. EU Regulation 1223/2009 status: permitted, max deo roll-on/gel 6.18%, deo spray antiperspirant 3.24%, aftershave 2.15%, EDP/EDT 0.05%, shampoo 7.14%, toothpaste 3.18% (as % Al in finished product per SCCS/1662/23). Industrial safety data is also available in the chemical safety database. Same-CAS public records also appear in industrial chemical safety data.

View industrial chemical safety profile for CAS 12042-91-0 →

Auto-generated CPSR Part A draft with source citations
Function
antiperspirant, astringent, deodorant
Safety Rating
GOOD

Chemistry & Identifiers

EC Number
234-933-1

Regulatory Status

EU EU Status permitted
EU Max Conc. deo roll-on/gel 6.18%, deo spray antiperspirant 3.24%, aftershave 2.15%, EDP/EDT 0.05%, shampoo 7.14%, toothpaste 3.18% (as % Al in finished product per SCCS/1662/23)
US US Status permitted
US Notes GRAS under OTC Monograph M019 (21 CFR Part 350); maximum 25% in antiperspirant products; regulated as OTC drug not cosmetic when used for antiperspirant claims; labeling must include kidney disease warning

For full compliance data across multiple jurisdictions, use the Substance Compliance tool.

Safety Data

Margin of Safety, dermal absorption, and sensitization profile summaries for Aluminum Chlorohydrate.

Calculate MoS for your specific formulation with the MoS Calculator.

Endocrine Disruptor Evidence (Expanded)

Cross-referenced EDC classifications, mechanism data, and dose-response evidence from EDLists, SIN List, and cosmetic-specific detail sources.

Cosmetic-Specific Mechanism
Category: heavy metal
Receptor targets: ERα
LOEC: 100 µM
EU status: allowed (max 25% anhydrous)

metalloestrogen; agonist (ERα)

Dose-Response Data Points
Endpoint Target Value Direction
dermal_intact skin 1.81 µg/cm² -
dermal_stripped skin 11.5 µg/cm² -

ECHA REACH Registration

European Chemicals Agency REACH dossier and Substances of Very High Concern listing.

Registration Type
Full
Tonnage Band
10,000 - 100,000 tonnes
Substance Type
SUBSTANCE
SVHC Candidate
No

Expanded Jurisdictional Detail

Additional regulatory detail beyond the 7-jurisdiction summary: Saudi SFDA, Korea MFDS, ASEAN ACD, Japan/Korea, Brazil/India, and cross-jurisdictional restriction entries.

JPKR Japan/Korea Cosmetics
Korea (Restricted): max 25.0
Additional Jurisdictional Restrictions (3)
Jurisdiction Status Max % Product Type
CN restricted 20 Antiperspirant/deodorant products
AU restricted - deodorants
GCC restricted 20.0 Antiperspirant products

Typical Use Concentrations

Reported concentration ranges per product category from SCCS/CIR/industry sources.

Product Category Typical Range Max Reported Source
Antiperspirant 5–25 25 CIR/VCRP

Additional Ingredient Properties

4 property records from structured ingredient metadata.

deodorant
{"cas_number": "1327-41-9", "ingredient_class": "antiperspirant_active", "mechanism_of_action": "sweat_gland_blocking", "antiperspirant_efficacy_sweat_reduction_pct": "20-50", "deodorant_efficacy_hours": "24", "odor_reduction_pct": "70-90", "bacteriostatic": "yes", "bactericidal": "no", "target_bacteria": "broad_spectrum", "microbiome_impact": "broad", "axillary_microbiome_effect": "reduces bacter…
ecotoxicity
{"biodegradable": "no", "biodegradation_days": "non-biodegradable", "bioaccumulative": "yes", "aquatic_toxicity_level": "moderate", "coral_reef_safe": "unknown", "marine_toxicity": "moderate toxicity", "freshwater_toxicity": "aluminum accumulation", "soil_toxicity": "metal accumulation", "endocrine_disruptor": "no", "persistent_organic_pollutant": "yes", "microplastic": "no", "nano_particle": "no"…
mineral_clay
{"cas_number": "12042-91-0", "ingredient_class": "other", "chemical_formula": "Al2Cl(OH)5", "mineral_origin": "synthetic", "particle_size_range_um": "1-50", "surface_area_m2_per_g": "5-30", "crystal_structure": "amorphous", "color_appearance": "white", "opacity": "opaque", "refractive_index": "1.62", "oil_absorption_g_per_100g": "60-150", "water_absorption_capacity": "low", "surface_charge_at_pH_7…
pediatric_safety
{"safe_for_newborn_0_6m": "avoid", "safe_for_infant_6_12m": "caution", "safe_for_toddler_1_3y": "caution", "safe_for_child_3_12y": "yes", "safe_for_teen_12_18y": "yes", "pediatric_max_concentration_pct": "0.0", "adult_max_concentration_pct": "25.0", "pediatric_dermal_absorption_factor": "moderate", "immature_skin_barrier_risk": "moderate", "oral_ingestion_risk": "low", "eye_irritation_risk": "low"…

Function Categories & List Membership

Cosmetic/Chemical Function Categories
Antiperspirant Astringent Deodorizer
Regulatory List Membership (1)
EU Restricted for Children (Cosmetics)

Expert Verdict

Expert safety assessment and concern-level summary for Aluminum Chlorohydrate.

Regulatory Flags

eu-not-annex-listed-but-sccs-limits-apply otc-drug-us not-cosmos-certifiable eu_children_restricted

Known Synonyms

Aluminium chloride hydroxide (Al2Cl(OH)5) Basic aluminum chloride [Al2(OH)5Cl] Aluminum chlorhydrol Basic aluminum chlorate EINECS 234-933-1 Locron Extra Locron flakes Macrospherical 95 Wickenol 321 Wickenol 323 Wickenol 324 UNII-407PSC3OC7

Chemical Function

Antiperspirant Astringent Deodorizer

Regulatory Lists

children; Europe; Personal care Canada; pharmaceutical inert_ingredient; non_food_use; Pesticides active_ingredient; Europe; Pesticides

Australian Status

AICIS status: listed

Frequently Asked Questions

Is Aluminum Chlorohydrate safe in cosmetics?

Aluminum Chlorohydrate has a safety rating of "GOOD" in our database. EU status: permitted. US status: permitted.

Is Aluminum Chlorohydrate allowed in the EU?

Aluminum Chlorohydrate EU regulatory status: permitted. Maximum allowed concentration: deo roll-on/gel 6.18%, deo spray antiperspirant 3.24%, aftershave 2.15%, EDP/EDT 0.05%, shampoo 7.14%, toothpaste 3.18% (as % Al in finished product per SCCS/1662/23). This is based on EU Regulation 1223/2009 and its amendments.

What does Aluminum Chlorohydrate do in cosmetics?

Aluminum Chlorohydrate functions as: antiperspirant, astringent, deodorant. It is classified as a Active Ingredient in our database. CAS number: 12042-91-0.

Is Aluminum Chlorohydrate used outside cosmetics?

Aluminum Chlorohydrate also appears in industrial chemical safety data. The cross-vertical cards on this page render same-CAS public rows from the matched databases.

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