Poor Cosmetic Ingredient NOAEL Data GHS Classified SCCS/CIR Reviewed

Ammonium Persulfate

Also known as: Peroxydisulfuric acid, diammonium salt, EINECS 231-786-5, Persulfate d'ammonium, UNII-22QF6L357F

INCI: AMMONIUM PERSULFATE

Ammonium Persulfate (CAS 7727-54-0) is a cosmetic cosmetic ingredient functioning as Oxidizing Agent, Bleaching Agent. NOAEL 41.1 mg/kg bw/day (cross-referenced against ToxValDB ECHA IUCLID); EU Regulation 1223/2009 status: permitted; 5 safety opinions reviewed (CIR Safety Assessment). Industrial safety data is also available in the chemical safety database. Same-CAS public records also appear in industrial chemical safety and pharmaceutical data.

View industrial chemical safety profile for CAS 7727-54-0 →

Auto-generated CPSR Part A draft with source citations
Function
Oxidizing Agent, Bleaching Agent
Safety Rating
POOR

Chemistry & Identifiers

Formula
H8N2O8S2
MW
228.21 g/mol
EC Number
231-786-5
PubChem CID
62648
IUPAC Name
diazanium;sulfonatooxy sulfate
InChIKey
ROOXNKNUYICQNP-UHFFFAOYSA-N

Regulatory Status

EU EU Status permitted
US US Status permitted
US Notes Not prohibited or specifically restricted by FDA for cosmetic use; 157 ingredient uses reported to FDA VCRP, 151 of which are in hair coloring/lightening products. CIR Expert Panel (2022 Amended Assessment, Int. J. Toxicol.) concluded safe as used as oxidizing agent in rinse-off hair colorants and lighteners; data insufficient to conclude safety in leave-on products and dentifrices.

For full compliance data across multiple jurisdictions, use the Substance Compliance tool.

Safety Data

Margin of Safety, dermal absorption, and sensitization profile summaries for Ammonium Persulfate.

Calculate MoS for your specific formulation with the MoS Calculator.

Toxicological Studies

10 study endpoints found for Ammonium Persulfate. NOAEL (No Observed Adverse Effect Level) values are used to calculate the Margin of Safety per SCCS methodology.

Endpoint Value Route Species Study Type Source
NOAEL =41.1 mg/kg bw/d oral rat inhalation toxicity CIR Safety Assessment
NOAEL =41.1 mg/kg bw/d oral rat inhalation toxicity CIR Safety Assessment
NOAEL =41.1 mg/kg bw/d oral rat inhalation toxicity CIR Safety Assessment
NOAEL =41.1 mg/kg bw/d oral rat inhalation toxicity CIR Safety Assessment
NOAEL =131.5 mg/kg bw/d oral rat inhalation toxicity CIR Safety Assessment
NOAEL =131.5 mg/kg bw/d oral rat inhalation toxicity CIR Safety Assessment
NOAEL =131.5 mg/kg bw/d oral rat inhalation toxicity CIR Safety Assessment
NOAEL =131.5 mg/kg bw/d oral rat inhalation toxicity CIR Safety Assessment
NOAEL =200 mg/kg bw/d oral rat repeated dose toxicity CIR Safety Assessment
NOAEL =200 mg/kg bw/d oral rat repeated dose toxicity CIR Safety Assessment

GHS Hazard Classification

Globally Harmonized System classification per ECHA C&L inventory and ILO/WHO International Chemical Safety Cards.

Short-term Exposure Effects
The substance is irritating to the eyes, skin and respiratory tract. Inhalation of dust may cause asthma-like reactions.
Long-term Exposure Effects
Repeated or prolonged inhalation may cause asthma. Repeated or prolonged contact with skin may cause dermatitis. Repeated or prolonged contact may cause skin sensitization. May cause a general allergic reaction, such as urticaria or shock.
Routes of Exposure
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

Safety Opinions

Official safety assessments from the Scientific Committee on Consumer Safety (SCCS) and Cosmetic Ingredient Review (CIR).

CIR Safety Assessment
Verdict: unknown
NOAEL: 41.1 mg/kg bw/d (oral)
CIR Safety Assessment
Verdict: unknown
NOAEL: 131.5 mg/kg bw/d (oral)
CIR Safety Assessment
Verdict: unknown
NOAEL: 80 mg/kg bw (oral)
CIR Safety Assessment
Verdict: unknown
NOAEL: 10.3 mg/m3 (inhalation)
CIR Safety Assessment
Verdict: unknown
NOAEL: 250 mg/kg/d (not specified)

Pre-Calculated Safety Assessment

Pre-calculated NOAEL → SED → MoS audit trail for Ammonium Persulfate across SCCS product categories, with measured dermal absorption where available.

EU CLP Annex VI Harmonized Classification

Legally binding harmonized classification per Regulation (EC) No 1272/2008 (CLP) Annex VI.

Signal Word
Danger
Pictograms
OxidiserHarmful / IrritantHealth Hazard
Hazard Class and Category
Ox. Sol. 3; Acute Tox. 4 *; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Resp. Sens. 1; Skin Sens. 1
Hazard Statements
  • H272 May intensify fire; oxidiser
  • H302 Harmful if swallowed
  • H335 May cause respiratory irritation
  • H315 Causes skin irritation
  • H319 Causes serious eye irritation
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
  • H317 May cause an allergic skin reaction

Inserted via ATP: CLP00

Endocrine Disruptor Evidence (Expanded)

Cross-referenced EDC classifications, mechanism data, and dose-response evidence from EDLists, SIN List, and cosmetic-specific detail sources.

Cosmetic-Specific Mechanism
Category: other
Receptor targets: TR (via iodide oxidation pathway)
LOEC: 1 µg/mL
EU status: restricted (exposure limit; EU 2022/1181)

modulator (thyroid oxidative pathway)

ECHA REACH Registration

European Chemicals Agency REACH dossier and Substances of Very High Concern listing.

Registration Type
Full
Tonnage Band
10,000 - 100,000 tonnes
Substance Type
SUBSTANCE
SVHC Candidate
No
Hazard classification: Restricted (Annex XVII)

Expanded Jurisdictional Detail

Additional regulatory detail beyond the 7-jurisdiction summary: Saudi SFDA, Korea MFDS, ASEAN ACD, Japan/Korea, Brazil/India, and cross-jurisdictional restriction entries.

Additional Jurisdictional Restrictions (1)
Jurisdiction Status Max % Product Type
IN restricted 11.0 hair bleaching powder products

Additional Ingredient Properties

1 property record from structured ingredient metadata.

hair_dye
{"cas_number": "7727-54-0", "ingredient_class": "bleaching_agent", "chemical_class": "other", "molecular_weight_Da": "228.20", "color_result_on_hair": "Lightening/decolorization", "shade_range": "blonde", "primary_function": "oxidizer", "requires_developer": "yes", "developer_volume_compatibility": "20/30/40", "lift_capability_levels": "3-5", "deposit_only": "no", "permanence": "permanent", "sensi…

PubChem Annotations

Safety and regulatory annotations from PubChem (NCBI) aggregated sources.

Safety (2)
ICSC Safety Card
0632
Source: WHO/JECFA
Skin Eye Respiratory Irritation
Exposure can irritate the skin, eyes, nose, throat adn lungs. Exposure may cause an allergy like reaction, with eye tearing, nose congestion, asthma like wheezing and difficulty in breathing. Life threatening shock may result.
Source: Hazardous Substances Data Bank (HSDB)
Regulatory (1)
JECFA Evaluation
AMMONIUM PERSULFATE | 1965 | Caution: Powerful oxidizing substance | NMRS 40/TRS 339-JECFA 9/15 | FAS 67.29/NMRS 40A,B,C-JECFA 9/119
Source: WHO/JECFA

Function Categories & List Membership

Cosmetic/Chemical Function Categories
Biocide Bleaching agent Catalyst Chemical reaction regulator Oxidizing agent
Regulatory List Membership (1)
FDA Substances Added to Food (EAFUS)

Expert Verdict

Expert safety assessment and concern-level summary for Ammonium Persulfate.

Regulatory Flags

oxidizing-agent hair-bleach strong-sensitizer respiratory-sensitizer occupational-asthma-risk contact-urticaria cir-safe-rinse-off-only ewg-unacceptable inorganic-salt insufficient-data-leave-on high-concern fda_food_additive

NOAEL Studies Summary

View details ->

Public NOAEL study rows linked to Ammonium Persulfate by CAS number or substance name.

Studies
16
Lowest NOAEL
41.1
Highest NOAEL
250

Units vary across source rows: mg/kg bw/d, mg/kg/d

CIR Safety Assessment

Known Synonyms

Peroxydisulfuric acid, diammonium salt EINECS 231-786-5 Persulfate d'ammonium UNII-22QF6L357F

Chemical Function

Oxidizing agent Bleaching agent Catalyst Chemical reaction regulator Biocide

Regulatory Lists

inert_ingredient; non_food_use; Pesticides fracking food_additive; Substances Added to Food (formerly EAFUS) (2/2019) fracking; water

Australian Status

AICIS status: listed_with_terms

Specific information requirements: Obligations to provide information apply. These obligations are: 1. If the assessment report about the chemical recommends secondary notification of the chemical in particular circumstances and any of the circumstances occur in relation to the introduction (importation or manufacture) of the chemical by a person, then the...

Cross-Vertical Safety Context

Same-CAS public records found in pharmaceutical data.

SOURCE ChEMBL / DrugCentral / FAERS DB_PHARMA CAS match

Pharmaceutical Data

Same-CAS rows from the pharmaceutical spoke database.

ChEMBL ID
CHEMBL2447905
View full pharmaceutical profile →

Frequently Asked Questions

Is Ammonium Persulfate safe in cosmetics?

Ammonium Persulfate has a safety rating of "POOR" in our database. EU status: permitted. US status: permitted. 10 toxicological study endpoint(s) are available in our database. This ingredient has been reviewed by CIR Safety Assessment.

Is Ammonium Persulfate allowed in the EU?

Ammonium Persulfate EU regulatory status: permitted. This is based on EU Regulation 1223/2009 and its amendments.

What does Ammonium Persulfate do in cosmetics?

Ammonium Persulfate functions as: Oxidizing Agent, Bleaching Agent. It is classified as a cosmetic ingredient in our database. CAS number: 7727-54-0.

What is the NOAEL for Ammonium Persulfate?

The NOAEL (No Observed Adverse Effect Level) for Ammonium Persulfate is =41.1 mg/kg bw/d based on a inhalation toxicity study via oral route in rat. A total of 10 study endpoints are available. Source: CIR Safety Assessment.

Is Ammonium Persulfate used outside cosmetics?

Ammonium Persulfate also appears in industrial chemical safety and pharmaceutical data. The cross-vertical cards on this page render same-CAS public rows from the matched databases.

Does Ammonium Persulfate have different safety status in cosmetics vs industrial chemicals?

Ammonium Persulfate is classified GHS Danger (H272, H302, H315, H317, H319, H334, H335, H320) in the chemicals database but is allowed in EU cosmetics.

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